Metal complexes of 15-membered triolefinic macrocycles, (E,E,Z)-1,6,11-tris[(2,4,6-triisopropylphenyl)sulfonyl]-1,6,11-triazacyclopentadeca-3,8,13-triene and its palladium(0), platinum(0), and silver(I) complexes

被引:10
作者
Cortès, J [1 ]
Moreno-Mañas, M [1 ]
Pleixats, R [1 ]
机构
[1] Univ Autonoma Barcelona, Dept Chem, E-08193 Barcelona, Spain
关键词
macrocycles; triene complexes; palladium; platinum; silver;
D O I
10.1016/S0040-4039(01)00758-4
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The preparation of the 15-membered macrocycle (E,E,Z)-1,6,11-tris[(2,4,6-triisopropylphenyl)sulfonyl]-1.6,11-triazacyclopentadeca-3,8,13-triene is reported. This cyclic triolefin forms stable complexes with palladium(0) and platinum(0), and a moderately stable complex with silver(I) tetrafluoroborate. (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:4337 / 4339
页数:3
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