A new strategy for the synthesis of spiro[4,5]decanes: A formal total synthesis of acorone

被引：9

作者：

Biju, PJ ^{[1
]}

Rao, GSRS ^{[1
]}

机构：

[1] Indian Inst Sci, Dept Organ Chem, Bangalore 560012, Karnataka, India

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 12期

关键词：

D O I：

10.1016/S0040-4039(99)00114-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new strategy for the construction of spiro[4,5]decanes is described and involves a bridgehead substitution of a methoxyl group in 6 by a methyl group, followed by an oxidative cleavage resulting in a stereogenic spirocentre which culminated in the formal synthesis of acorone. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：2405 / 2406

页数：2

共 17 条

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