Structural and magnetic properties of a novel ferrocenyl-diiodine charge transfer complex

被引：20

作者：

Allen, DW

Berridge, R

Bricklebank, N

Forder, SD

Palacio, F

Coles, SJ

Hursthouse, MB

Skabara, PJ

机构：

[1] Sheffield Hallam Univ, Inst Mat Res, Sheffield S1 1WB, S Yorkshire, England

[2] Univ Zaragoza, Inst Ciencia Mat Aragon, CSIC, E-50009 Zaragoza, Spain

[3] Univ Southampton, Dept Chem, Southampton SO17 1BJ, Hants, England

[4] Univ Manchester, Dept Chem, Manchester M13 9PL, Lancs, England

来源：

INORGANIC CHEMISTRY | 2003年 / 42卷 / 13期

关键词：

D O I：

10.1021/ic034092f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of 4-ferrocenyl-1,3-dithiole-2-thione with diiodine affords an unprecedented "double" charge-transfer complex; the highly ordered ferrocenium units are held by a supramolecular polyiodide chain, and the material shows evidence of the formation of zigzag magnetic chains below 2 K.

引用

页码：3975 / 3977

页数：3

共 18 条

[1]

Aragoni MC, 2001, CHEM-EUR J, V7, P3122, DOI 10.1002/1521-3765(20010716)7:14<3122::AID-CHEM3122>3.0.CO

[2]

2-H

[3] Structure and bonding of diiodine adducts of the sulfur-rich donors 1,3-dithiacyclohexane-2-thione (ptc) and 4,5-ethylenedithio-1,3-dithiole-2-thione (ttb) [J].