Mass spectrometric study of UO2-ZrO2 pseudo-binary system

被引:25
作者
Baïchi, M
Chatillon, C
Guèneau, C
Chatain, S
机构
[1] CEA Grenoble, LARA, SECI, DEC,DRN, F-38054 Grenoble, France
[2] Ecole Natl Super Electrochim & Electrome Grenoble, Inst Natl Polytech Grenoble, CNRS, UMR 5614,Lab Thermodynam & Physicochim Met, F-38402 St Martin Dheres, France
[3] CEA Saclay, LEPCA, SPCP, DPE,DCC, F-91191 Gif Sur Yvette, France
关键词
D O I
10.1016/S0022-3115(01)00477-9
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
thermodynamic activity of UO2 in the UO2-ZrO2 pseudo-binary system, for fractional concentrations of ZrO2 from 0 to 1 in the 2000-2400 K temperature range was investigated by partial pressure measurements of UO2 (g) using the multiple Knudsen cell-mass spectrometric method. This system exhibits a positive deviation from the ideal behavior at 2200 K and becomes close to ideal near 2500 K. (C) 2001 Published by Elsevier Science B.V.
引用
收藏
页码:84 / 87
页数:4
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