Interfacial molecular recognition between polysaccharides and calcium carbonate during crystallization

被引：42

作者：

Yang, L ^{[1
]}

Zhang, XY ^{[1
]}

Liao, ZJ ^{[1
]}

Guo, YM ^{[1
]}

Hu, ZG ^{[1
]}

Cao, Y ^{[1
]}

机构：

[1] Henan Normal Univ, Coll Chem & Environm Sci, Xinxiang 453002, Peoples R China

来源：

JOURNAL OF INORGANIC BIOCHEMISTRY | 2003年 / 97卷 / 04期

基金：

中国国家自然科学基金;

关键词：

beta-cyclodextrin; polysaccharides; calcium carbonate; interfacial molecular recognition;

D O I：

10.1016/S0162-0134(03)00311-8

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Based on the basic principles of biomineralization, using beta-cyclodextrin, hepatin and soluble starch as organic matrices, employing the biomimetic method, the crystallization of CaCO3 was studied by Fourier transform infrared spectroscopy (FT-IR), X-ray powder diffraction analysis (XRD), scanning electronic microscopy (SEM), thermal gravity-differential thermal analysis and conductivity analysis. The results show that polysaccharides have an effect on the crystallization of CaCO3. CaCO3 crystals also have an effect on polysaccharides. The possible mechanism of this interaction is discussed. (C) 2003 Elsevier Inc. All rights reserved.

引用

页码：377 / 383

页数：7

共 19 条

[1] Polysaccharides of intracrystalline glycoproteins modulate calcite crystal growth in vitro [J].

Albeck, S ;

Weiner, S ;

Addadi, L .

CHEMISTRY-A EUROPEAN JOURNAL, 1996, 2 (03) :278-284

[2] Aragonite crystallization in primary cell cultures of multicellular isolates from a hard coral, Pocillopora damicornis [J].

Domart-Coulon, IJ ;

Elbert, DC ;

Scully, EP ;

Calimlim, PS ;

Ostrander, GK .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2001, 98 (21) :11885-11890

[3] Control of aragonite or calcite polymorphism by mollusk shell macromolecules [J].

Falini, G ;

Albeck, S ;

Weiner, S ;

Addadi, L .

SCIENCE, 1996, 271 (5245) :67-69

[4]

Guo YM, 2001, ACTA CHIM SINICA, V59, P755

[5] Structural aspects of stereodifferentiation in the solid state [J].

Harata, K .

CHEMICAL REVIEWS, 1998, 98 (05) :1803-1827

[6]

Lehn J. M., 1995, SUPRAMOLECULAR CHEM

[7]

Leiserowitz L, 1992, ANGEW CHEM, V104, P134

[8] Porous bioactive calcium carbonate implants processed by starch consolidation [J].

Lemos, AF ;

Ferreira, JMF .

MATERIALS SCIENCE & ENGINEERING C-BIOMIMETIC AND SUPRAMOLECULAR SYSTEMS, 2000, 11 (01) :35-40

[9] BIOMINERALIZATION AND BIOMIMETIC MATERIALS CHEMISTRY [J].

MANN, S .

JOURNAL OF MATERIALS CHEMISTRY, 1995, 5 (07) :935-946

[10]

Marsh M E, 1999, Gravit Space Biol Bull, V12, P5

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