Molecular structures of 1,12-B12H10(CO)2 and its dihydrate 1,12-B12H10[C(OH)2]2 -: a novel bis-carbene complex

被引：19

作者：

Fox, MA ^{[1
]}

Howard, JAK ^{[1
]}

Moloney, JM ^{[1
]}

Wade, K ^{[1
]}

机构：

[1] Univ Durham, Sci Labs, Dept Chem, Durham DH1 3LE, England

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 22期

关键词：

D O I：

10.1039/a806898d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Crystal structures of the dicarbonyl 1,12-B12H10(CO)(2) and its hydrated form 1,12-B12H10(CO2H2)(2). 4H(2)O show little pi-bond character in their B-C bonds but contain significant distortions from the regular B-12 icosahedron geometry; the hydrate, until now thought to be a hydroxonium salt, contains dihydroxycarbene ('protonated carboxylic acid') ligands C(OH)(2).

引用

页码：2487 / 2488

页数：2

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