Tetramethylethylene diamine trimethylsilyl chloride mediated addition of benzyl copper reagents to alpha,beta-unsaturated esters

被引：20

作者：

vanHeerden, PS

Bezuidenhoudt, BCB

Ferreira, D

机构：

[1] Department of Chemistry, University of the Orange Free State, Bloemfontein, 9300

来源：

TETRAHEDRON | 1996年 / 52卷 / 37期

关键词：

D O I：

10.1016/0040-4020(96)00718-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Several benzylic copper reagents, benzylcopper, 4-methoxybenzylcopper and 1-phenylethylcopper, facilitate the conjugate addition of the corresponding benzyl ligands to alpha,beta-enoates in the presence of tetramethylethylene diamine and trimethylsilyl chloride in high yields. Copyright (C) 1996 Published by Elsevier Science Ltd

引用

页码：12313 / 12322

页数：10

共 34 条

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