Polymeric transition metal complexes of 1,4-bis-(4-pyridylsulfenylmethyl)benzene and of its 2-pyridyl analogue

被引：18

作者：

Atherton, Z ^{[1
]}

Goodgame, DML ^{[1
]}

Menzer, S ^{[1
]}

Williams, DJ ^{[1
]}

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England

来源：

POLYHEDRON | 1998年 / 18卷 / 1-2期

基金：

英国工程与自然科学研究理事会;

关键词：

X-ray structure; polymeric complexes; bis(pyridine) ligands;

D O I：

10.1016/S0277-5387(98)00295-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The preparations are reported of a range of complexes of Mn-II, Co-II, Ni-II and Cu-II with 1,4-bis-(4-pyridylsulfenylmethyl)benzene (B4PSB) and of complexes of Co-II, Ni-II and Cu-II with the 2-pyridyl analogue (B2PSB), together with relevant spectroscopic data. X-Ray crystallographic studies on Co(B2PSB)(NO3)(2) show the presence of a chain structure in which five-coordinate cobalt centers are linked by bridging (B2PSB) ligands, with the remaining coordination sites about each metal atom being occupied by one very asymmetrically chelating nitrate group and an oxygen atom of a unidentate nitrate. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：273 / 279

页数：7

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