First spectroscopic evidence for molecular HCl on a liquid surface with sum frequency generation

被引：52

作者：

Baldelli, S ^{[1
]}

Schnitzer, C ^{[1
]}

Shultz, MJ ^{[1
]}

机构：

[1] Tufts Univ, Dept Chem, Medford, MA 02155 USA

来源：

JOURNAL OF CHEMICAL PHYSICS | 1998年 / 108卷 / 23期

关键词：

D O I：

10.1063/1.476456

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Sum frequency generation spectroscopy has been used to obtain the vibrational spectrum of HCl on the surface of a liquid. HCl was studied on the surface of 96 wt % H(2)SO(4), 12 M HCl solution, liquid HCl and glass, of which only liquid HCl produces a resonant signal. Implications for the form of HCl on surfaces and the reactions in the atmosphere are discussed. (C) 1998 American Institute of Physics.

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页码：9817 / 9820

页数：4

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