K10M4Sn4S17 (M = Mn, Fe, Co, Zn):: Soluble quaternary sulfides with the discrete [M4Sn4S17]10-supertetrahedral clusters

被引：95

作者：

Palchik, O ^{[1
]}

Iyer, RG ^{[1
]}

Liao, JH ^{[1
]}

Kanatzidis, MG ^{[1
]}

机构：

[1] Michigan State Univ, Dept Chem, E Lansing, MI 48824 USA

来源：

INORGANIC CHEMISTRY | 2003年 / 42卷 / 17期

关键词：

D O I：

10.1021/ic034600l

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Four cubic compounds are reported that contain the supertetrahedral cluster [M4Sn4S17](10-) where M = Mn, Fe, Co, Zn. The cluster features a central quadruply bridging sulfide ion (mu(4)-S) that holds together four divalent M atoms in a tetrahedral arrangement. This core is capped with four tridentate [SnS4](4-) fragments to complete the structure.

引用

页码：5052 / 5054

页数：3

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