Electrochemical and Microstructural Evaluation of Aged Nanostructured Thin Film Fuel Cell Electrocatalyst

被引:28
作者
Kongkanand, Anusorn [1 ]
Liu, Zhongyi [1 ]
Dutta, Indrajit [2 ]
Wagner, Frederick T. [1 ]
机构
[1] Gen Motors Global Res & Dev, Electrochem Energy Res Lab, Honeoye Falls, NY 14472 USA
[2] Trison Business Solut Inc, Leroy, NY 14482 USA
关键词
OXYGEN REDUCTION; PLATINUM MONOLAYER; CATALYST LAYERS; PARTICLE-SIZE; DISSOLUTION; MEMBRANE; INSTABILITY; ELECTRODES; ALLOY; MN;
D O I
10.1149/2.013111jes
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
3M's Nanostructured Thin Film (NSTF) electrode offers an alternative path to reduce Pt cost in a polymer electrolyte membrane fuel cell, owing to its unique extended surface structure. To understand the fuel cell performance and the durability of the electrode, it is necessary to know its microstructure. In this report, electrochemical and microstructural evaluations of the NSTF electrodes were done after different stages of ageing in a fuel cell. Changes over time of surface roughness, dealloying, and microstructure were observed. Correlations between NSTF electrode structure and fuel cell performance are discussed. (C) 2011 The Electrochemical Society. [DOI: 10.1149/1.013111jes] All rights reserved.
引用
收藏
页码:B1286 / B1291
页数:6
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