Vapour-liquid equilibria in the binary and ternary mixtures of methyl benzoate, methyl p-toluate and dimethyl terephthalate

被引：19

作者：

Semeniuk, B ^{[1
]}

Wilczura-Wachnik, H ^{[1
]}

机构：

[1] Univ Warsaw, Dept Chem, PL-02093 Warsaw, Poland

来源：

FLUID PHASE EQUILIBRIA | 1998年 / 152卷 / 02期

关键词：

experiment; data; VLE low pressure; benzenecarboxylic acids esters; dimethyl terephthalate;

D O I：

10.1016/S0378-3812(98)00205-2

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Low pressure isobaric T-x-y data were determined for methyl benzoate-methyl p-toluate, methyl benzoate-dimethyl terephthalate and methyl p-toluate-dimethyl terephthalate systems at 6.6 and 13.3 kPa, as well as for some methyl benzoate-methyl p-toluate-dimethyl terephthalate ternary mixtures at 6.6 kPa. Both vapour pressures of two pure components and P-x isotherms for all three binaries at 433.15 K were also measured. The ebulliometer-type equilibrium still with manostat and an additional thermostat was used in all measurements. Liquid and vapour compositions were determined by g.l.c. Experimental equilibrium data were fitted to Redlich-Kister, Wilson, NRTL and UNIQUAC equations. Some predictions with UNIFAC method were also made. (C) 1998 Elsevier Science B.V. All rights reserved.

引用

页码：337 / 345

页数：9

共 16 条

[1] STATISTICAL THERMODYNAMICS OF LIQUID-MIXTURES - NEW EXPRESSION FOR EXCESS GIBBS ENERGY OF PARTLY OR COMPLETELY MISCIBLE SYSTEMS [J].