Effect of Zn loading of the Pt-Zn-HY trifunctional catalysts on the hydroisomerization of n-heptane

被引：37

作者：

Saberi, MA ^{[1
]}

Le van Mao, R ^{[1
]}

Martin, M ^{[1
]}

Mak, AWH ^{[1
]}

机构：

[1] Concordia Univ, Dept Chem & Biochem, Labs Adv Inorgan Mat & Ind Catalysis, Montreal, PQ H3G 1M8, Canada

来源：

APPLIED CATALYSIS A-GENERAL | 2001年 / 214卷 / 02期

关键词：

n-heptane hydroisomerization; Zn modified Pt-Hy zeolite catalysts; desorption-transfer promoting sites; trifunctional catalysts;

D O I：

10.1016/S0926-860X(01)00493-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The zinc loading needed for having the maximum activity of isomerization, increases with increasing reaction temperature. This means that a stronger cracking activity requires a higher amount of zinc species, the latter being in the cationic form. In the context of the hypothesis of trifunctional catalyst configuration, the new set of results provides another piece of experimental evidence for the desorption-transfer promoting role of the zinc species whose Lewis acid character appears to play an important role in the enhancement of the isomerization activity. Thus, it is possible to achieve higher isomerization performance by using the trifunctional catalysts at lower reaction temperature and longer contact time. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：229 / 236

页数：8

共 13 条

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