Optically active transition metal complexes .111. Synthesis and structure of a new thioamidato rhodium(I) complex

被引：15

作者：

Brunner, H ^{[1
]}

Bugler, J ^{[1
]}

Nuber, B ^{[1
]}

机构：

[1] UNIV HEIDELBERG,INST ANORGAN CHEM,D-69120 HEIDELBERG,GERMANY

来源：

TETRAHEDRON-ASYMMETRY | 1996年 / 7卷 / 11期

关键词：

D O I：

10.1016/0957-4166(96)00406-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of [Rh(cod)Cl](2) with deprotonated N-[(A)-1-phenylethyl]thiobenzamide affords the new complex 1. In the solid state 1 exists as a binuclear complex with the two sulfur atoms of two thioamidato ligands bridging the Rh atoms. The molecular structure of 1 was determined by X-ray analysis: C46H52N2S2Rh2, monoclinic, space group C2, a - 10.564(4), b = 16.864(5), c = 23.548(7), beta = 95.05(3)degrees, Z = 2 x 2, R = 0.046, R(w) = 0,039. Complex 1 equilibrates with an isomer in solution at room temperature. Copyright (C) 1996 Published by Elsevier Science Ltd

引用

页码：3095 / 3098

页数：4

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