The curing reaction study of the active material in the lead-acid battery

被引:16
作者
Laruelle, S [1 ]
Grugeon-Dewaele, S
Torcheux, L
Delahaye-Vidal, A
机构
[1] Univ Picardie, Lab Reactivite & Chim Solides, UPRESA 6007, F-80039 Amiens, France
[2] CEAC, F-92636 Gennevilliers, France
关键词
lead-acid batteries; lead sulphates; polyvinylpyrrolidone; morphology control; curing;
D O I
10.1016/S0378-7753(98)00187-6
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A study of the curing reaction involved in the positive plate of the lead-acid battery has been undertaken. The variation of the different parameters of the curing reaction has shown the possibility of changing the 4BS needles dimensions. In particular, the addition of a surfactant agent, namely the polyvinylpyrrolidone, to the reagents allows the obtention of tailor-made 4BS particles useable in the industrial preparation of the positive plates. (C) 1999 Elsevier Science S.A. All rights reserved.
引用
收藏
页码:83 / 89
页数:7
相关论文
共 10 条
[1]   TETRABASIC LEAD SULFATE AS A PASTE MATERIAL FOR POSITIVE PLATES [J].
BIAGETTI, RV ;
WEEKS, MC .
BELL SYSTEM TECHNICAL JOURNAL, 1970, 49 (07) :1305-+
[2]  
Bode H., 1977, LEAD ACID BATTERIES
[3]  
BODE H, 1959, ELECTROCHIM ACTA, V1, P318
[4]   FORMATION OF TETRABASIC LEAD SULFATE AT ROOM-TEMPERATURE [J].
CHANG, TG ;
WRIGHT, MM .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1981, 128 (04) :719-725
[5]   Soaking and formation of tetrabasic lead sulfate [J].
GrugeonDewaele, S ;
Leriche, JB ;
Tarascon, JM ;
DelahayeVidal, A ;
Torcheux, L ;
Vaurijoux, JP ;
Henn, F ;
DeGuibert, A .
JOURNAL OF POWER SOURCES, 1997, 64 (1-2) :71-80
[6]  
GRUGEONDEWAELE S, IN PRESS J ELECTROCH
[7]   INFLUENCE OF PBO MODIFICATION ON THE KINETICS OF THE 4PBO.PBSO4 LEAD-ACID-BATTERY PASTE FORMATION [J].
ILIEV, V ;
PAVLOV, D .
JOURNAL OF APPLIED ELECTROCHEMISTRY, 1979, 9 (05) :555-562
[8]   IMPROVING THE CURING OF POSITIVE PLATES FOR LEAD-ACID-BATTERIES [J].
RAND, DAJ ;
HILL, RJ ;
MCDONAGH, M .
JOURNAL OF POWER SOURCES, 1990, 31 (1-4) :203-215
[9]  
TOTORCHEUX L, 1996, P LABAT 96, P153
[10]  
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