Characterization of nanocomposite materials prepared via laser ablation of Pt/TiO2 bi-combinant targets

被引:18
作者
Beck, KM
Sasaki, T
Koshizaki, N
机构
[1] Pacific NW Lab, William R Wiley Environm Mol Sci Lab, Richland, WA 99352 USA
[2] Agcy Ind Sci & Technol, Natl Inst Mat & Chem Res, Tsukuba, Ibaraki 3058565, Japan
基金
美国国家科学基金会;
关键词
D O I
10.1016/S0009-2614(99)00022-6
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Pt/TiO2 thin-film nanocomposites have been prepared using a process of bi-combinant-target pulsed-laser deposition. Pt nanoparticles have been produced, possibly in the deposition process through rapid surface diffusion. The nanocomposite films can be created with the anatase form of TiO2 being the dominant crystal structure. The Pt nanoparticles are similar to 30 nm in size and homogeneously distributed. Within the nanocomposite films, a similar to 5% Pt atomic concentration can be synthesized from 20% Pt by weight bi-combinant targets. These thin films exhibit an optical bandgap less than 2.3 eV and a photoluminescence emission between 680 and 800 nm. (C) 1999 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:336 / 342
页数:7
相关论文
共 17 条
[1]   INVESTIGATION OF OPTICALLY ALLOWED TRANSITIONS OF ALPHA-SULFUR THIN-FILMS [J].
ABASS, AK ;
HASEN, AK ;
MISHO, RH .
JOURNAL OF APPLIED PHYSICS, 1985, 58 (04) :1640-1642
[2]   CHARACTERIZATION OF TIO2 FILMS MODIFIED BY PLATINUM DOPING [J].
AVALLE, L ;
SANTOS, E ;
LEIVA, E ;
MACAGNO, VA .
THIN SOLID FILMS, 1992, 219 (1-2) :7-17
[3]   EXCIMER-LASER SPUTTERING DEPOSITION OF TIO2 OPTICAL COATING FOR SOLAR-CELLS [J].
DURAND, HA ;
BRIMAUD, JH ;
HELLMAN, O ;
SHIBATA, H ;
SAKURAGI, S ;
MAKITA, Y ;
GESBERT, D ;
MEYRUEIS, P .
APPLIED SURFACE SCIENCE, 1995, 86 (1-4) :122-127
[4]   Time-resolved imaging of gas phase nanoparticle synthesis by laser ablation [J].
Geohegan, DB ;
Puretzky, AA ;
Duscher, G ;
Pennycook, SJ .
APPLIED PHYSICS LETTERS, 1998, 72 (23) :2987-2989
[5]  
GEOHEGAN DB, COMMUNICATION
[7]  
KAWAGUCHI T, 1969, TOKYO GAKUGEI DAIGAK, V21, P78
[8]   HETEROGENEOUS PHOTOCATALYTIC DECOMPOSITION OF SATURATED CARBOXYLIC-ACIDS ON TIO2 POWDER - DECARBOXYLATIVE ROUTE TO ALKANES [J].
KRAEUTLER, B ;
BARD, AJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (19) :5985-5992
[9]  
KREIBIG U, 1993, OPTICAL PROPERTIES M, P358
[10]   Shape transition of germanium nanocrystals on a silicon (001) surface from pyramids to domes [J].
Medeiros-Ribeiro, G ;
Bratkovski, AM ;
Kamins, TI ;
Ohlberg, DAA ;
Williams, RS .
SCIENCE, 1998, 279 (5349) :353-355