Diffusion coefficients in ionic liquids: Relationship to the viscosity

被引：69

作者：

Brookes, R ^{[1
]}

Davies, A ^{[1
]}

Ketwaroo, G ^{[1
]}

Madden, PA ^{[1
]}

机构：

[1] Univ Oxford, Dept Chem, Oxford OX1 3QZ, England

来源：

JOURNAL OF PHYSICAL CHEMISTRY B | 2005年 / 109卷 / 14期

关键词：

D O I：

10.1021/jp046355c

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The relationship between the diffusion coefficient and the viscosity has been examined in computer simulations for a number of ions diffusing in a molten salt (alkali halide) solvent. The comparison gives a measure of a hydrodynamic radius for the diffusing ions which is then compared with the bare ionic radius and a characteristic radius of the coordination complex formed by halide ions around polyvalent cations. K+ and Cl- ions appear to diffuse as isolated spherical particles, whereas the trivalent cations Sc3+, Y3+, and La3+ diffuse as if with an intact coordination shell. These different behaviors can be related to the time scale for the relaxation of the coordination shell, compared to the structural relaxation time of the solvent.

引用

页码：6485 / 6490

页数：6

共 33 条

[1]

[Anonymous], FLUID MECH

[2]

BOCKRIS JO, 1955, MODERN ELECTROCHEMIS

[3] ROUGH HARD-SPHERE THEORY OF SELF-DIFFUSION CONSTANT FOR MOLECULAR LIQUIDS [J].