Binaphtholato complexes of tungsten(VI) from tris(1,2-ethanediolato)tungsten(VI). Synthesis and X-ray structures of [W(bino)(diolato)2] complexes

被引：9

作者：

Lehtonen, A ^{[1
]}

Sillanpää, R ^{[1
]}

机构：

[1] Univ Turku, Dept Chem, FIN-20014 Turku, Finland

来源：

POLYHEDRON | 2000年 / 19卷 / 26-27期

基金：

芬兰科学院;

关键词：

binaphtholato complexes; tungsten(VI); x-ray structures;

D O I：

10.1016/S0277-5387(00)00560-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Racemic 6,6'-disubstituted-1,1'-bi-2-naphthols H(2)X(2)bino (X = H, Br) and corresponding binaphthyl acetates react with trisdiolatetungsten(VI) complexes [W(eg)(3)] and [W(eg)(pin)(2)] (eg = ethanediolate dianion, pin = pinacolate dianion) forming heteroleptic complexes [W(X(2)bino)(diolato)(2)]. The X-ray crystal structure determinations confirmed that the isolated compounds are made of monomeric tris(diolate)tungsten(VI) molecules in which the central tungsten atom is bonded to six oxygen atoms forming a distorted octahedral coordination sphere around the metal ion. (C) 2000 Elsevier Science B.V. All rights reserved.

引用

页码：2579 / 2584

页数：6

共 19 条

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[2]

2-N

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