Nitrogen- and phosphorus-coordinated nickel(II) complexes as catalysts for the oligomerization of ethylene

被引：31

作者：

Bluhm, ME ^{[1
]}

Folli, C ^{[1
]}

Walter, O ^{[1
]}

Döring, M ^{[1
]}

机构：

[1] Forschungszentrum Karlsruhe, Inst Chem Tech, ITC CPV, D-76021 Karlsruhe, Germany

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2005年 / 229卷 / 1-2期

关键词：

dimerization; oligomerization; diimine complexes; catalysts; ethylene; Schiff base complexes;

D O I：

10.1016/j.molcata.2004.11.015

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Nitrogen- and phosphorus-coordinated nickel(II) complexes 1 and 2 are active precatalysts together with the cocatalyst MAO for the oligomerization of ethylene mainly favoring the production of butenes. The nickel(II) complex 2b reveals a good selectivity at higher ethylene pressure for the production of 1-butene. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：177 / 181

页数：5

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