Exceptionally low-temperature carbon-hydrogen/carbon-deuterium exchange reactions of organic and organometallic compounds catalyzed by the Cp*(PMe3)IrH(ClCH2Cl)+ cation

被引：131

作者：

Golden, JT

Andersen, RA ^{[1
]}

Bergman, RG

机构：

[1] Univ Calif Berkeley, Lawrence Berkeley Lab, Div Chem Sci, Berkeley, CA 94720 USA

[2] Univ Calif Berkeley, Dept Chem, Ctr New Direct Organ Synth, Berkeley, CA 94720 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2001年 / 123卷 / 24期

关键词：

D O I：

10.1021/ja0155480

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

No abstract available

引用

页码：5837 / 5838

页数：2

共 23 条

[1] Alkylation of iridium via tandem carbon-hydrogen bond activation/decarbonylation of aldehydes. Access to complexes with tertiary and highly hindered metal-carbon bonds [J].

Alaimo, PJ ;

Arndtsen, BA ;

Bergman, RG .

ORGANOMETALLICS, 2000, 19 (11) :2130-2143

[2] SELECTIVE INTERMOLECULAR CARBON-HYDROGEN BOND ACTIVATION BY SYNTHETIC METAL-COMPLEXES IN HOMOGENEOUS SOLUTION [J].

ARNDTSEN, BA ;

BERGMAN, RG ;

MOBLEY, TA ;

PETERSON, TH .

ACCOUNTS OF CHEMICAL RESEARCH, 1995, 28 (03) :154-162

[3] UNUSUALLY MILD AND SELECTIVE HYDROCARBON C-H BOND ACTIVATION WITH POSITIVELY CHARGED IRIDIUM(III) COMPLEXES [J].

ARNDTSEN, BA ;

BERGMAN, RG .

SCIENCE, 1995, 270 (5244) :1970-1973

[4] ACTIVATION OF CARBON-HYDROGEN BONDS IN ALKANES AND OTHER ORGANIC-MOLECULES BY IR(I), RH(I) AND IR(III) COMPLEXES [J].

BENGALI, AA ;

ARNDTSEN, BA ;

BURGER, PM ;

SCHULTZ, RH ;

WEILLER, BH ;

KYLE, KR ;

MOORE, CB ;

BERGMAN, RG .

PURE AND APPLIED CHEMISTRY, 1995, 67 (02) :281-288

[5] A STRUCTURAL, KINETIC, AND THERMODYNAMIC STUDY OF THE REVERSIBLE THERMAL C-H ACTIVATION REDUCTIVE ELIMINATION OF ALKANES AT IRIDIUM [J].

BUCHANAN, JM ;

STRYKER, JM ;

BERGMAN, RG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (07) :1537-1550

[6] Synthesis of fluorophenyl derivatives of iron, molybdenum and tungsten via B(C6F5)(3) and unusual carbon-fluorine bond reactions [J].

Chernega, AN ;

Graham, AJ ;

Green, MLH ;

Haggitt, J ;

Lloyd, J ;

Mehnert, CP ;

Metzler, N ;

Souter, J .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (13) :2293-2303

[7] ASPECTS OF METHANE CHEMISTRY [J].

CRABTREE, RH .

CHEMICAL REVIEWS, 1995, 95 (04) :987-1007

[8] SYNTHESIS OF TRIMETHYLPHOSPHINE-SUBSTITUTED (PENTAMETHYLCYCLOPENTADIENYL)IRIDIUM HYDRIDE COMPLEXES - PROTONATION AND DEPROTONATION OF (C5(CH3)5)IR(P(CH3)3)H2 [J].

GILBERT, TM ;

BERGMAN, RG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (12) :3502-3507

[9] A combined experimental and density functional theory investigation of hydrocarbon activation at a cationic platinum(II) diimine aqua complex under mild conditions in a hydroxylic solvent [J].

Heiberg, H ;

Johansson, L ;

Gropen, O ;

Ryan, OB ;

Swang, O ;

Tilset, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (44) :10831-10845

[10] Quantum mechanical exchange coupling in iridium trihydride complexes [J].

Heinekey, DM ;

Hinkle, AS ;

Close, JD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (23) :5353-5361

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