Morphological control and molecular recognition by bis-urea hydrogen bonding in micelles of amphiphilic tri-block copolymers

被引:83
作者
Chebotareva, N
Bomans, PHH
Frederik, PM
Sommerdijk, NAJM
Sijbesma, RP
机构
[1] Eindhoven Univ Technol, Dept Chem Engn, NL-5600 MB Eindhoven, Netherlands
[2] Univ Maastricht, EM Unit, NL-6229 ER Maastricht, Netherlands
关键词
D O I
10.1039/b507171b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Hydrogen bonding between urea groups of amphiphilic triblock copolymers considerably affects their self-assembly in water, which results in a strong modification of morphology and viscosity of aqueous solutions; the hydrogen bonding motif in these amphiphilic copolymers allows molecular recognition of small molecules with complementary hydrogen bonding units.
引用
收藏
页码:4967 / 4969
页数:3
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