Polymer-ceramic ion-conducting composites

被引：48

作者：

Nairn, K ^{[1
]}

Forsyth, M ^{[1
]}

Every, H ^{[1
]}

Greville, M ^{[1
]}

MacFarlane, DR ^{[1
]}

机构：

[1] MONASH UNIV,DEPT CHEM,CLAYTON,VIC 3168,AUSTRALIA

来源：

SOLID STATE IONICS | 1996年 / 86-8卷

关键词：

polymer-ceramic composites; composite electrolytes; ion conduction;

D O I：

10.1016/0167-2738(96)00212-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Composites of a Li+ ion-conducting ceramic powder in a polyether-based elastomeric electrolyte matrix are described. At 66 wt.% of ceramic the composite can be prepared as a paste and cured into a coherent material having useful elastic and tensile properties. The total conductivity of the composite was found to be (1.9+/-0.2) x 10(-4) S cm(-1) at 40 degrees C which was approximately 1 order of magnitude higher than the polymer electrolyte component alone. The result was also approximately 1 order of magnitude higher than the total conductivity of the ceramic powders tested in this work.

引用

页码：589 / 593

页数：5

共 11 条

[1] IONIC-CONDUCTIVITY OF THE LITHIUM TITANIUM PHOSPHATE (LI1+XALXTI2-X(PO4)3), (LI1+XSCXTI2-X(PO4)3), (LI1+XYXTI2-X(PO4)3), (LI1+XLAXTI2-X(PO4)3 SYSTEMS [J].