Synthesis of a tetrahomodioxacalix[4]arene tetraamide and the crystal structure of its lead ion complex

被引：26

作者：

No, KH

Kim, JS ^{[1
]}

Shon, OJ

Yang, SH

Suh, IH

Kim, JG

Bartsch, RA

Kim, JY

机构：

[1] Konyang Univ, Dept Chem, Nonsan 320711, South Korea

[2] Sookmyung Womens Univ, Dept Chem, Seoul 140742, South Korea

[3] Chungnam Natl Univ, Dept Phys, Taejon 305764, South Korea

[4] Texas Tech Univ, Dept Chem & Biochem, Lubbock, TX 79409 USA

[5] Korea Ginseng & Tobacco Res Inst, Taejon 305345, South Korea

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2001年 / 66卷 / 18期

关键词：

D O I：

10.1021/jo0101656

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The 1,4-altemate tetrahomodioxacalix[4]arene tetraamide 4 with four p-phenyl groups on its upper rim was synthesized. In two-phase metal picrate extraction, 4 exhibited Pb2+ selectivity with formation of a 1:1 complex in chloroform. In the solid-state structure of the 4 . Pb(Pic)(2) complex, Pb2+ is bound by the carbonyl oxygens of two adjacent amide groups and an aryl-alkyl ether oxygen atom of one of these amide-containing substituents. The crystal structure and H-1 NMR spectrum of the 4 . Pb2+ complex reveals pi -metal ion complexation of one aromatic ring in the ligand with Pb2+.

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页码：5976 / 5980

页数：5

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