Interaction of epoxy model molecules with aluminium, anodised titanium and copper surfaces: an XPS study

被引：83

作者：

Marsh, J ^{[1
]}

Minel, L ^{[1
]}

Barthes-Labrousse, MG ^{[1
]}

Gorse, D ^{[1
]}

机构：

[1] CNRS, Ctr Etud Chim Met, F-94407 Vitry, France

来源：

APPLIED SURFACE SCIENCE | 1998年 / 133卷 / 04期

关键词：

epoxy model molecules; aluminium; anodised titanium; copper surfaces; X-ray photoelectron spectroscopy (XPS);

D O I：

10.1016/S0169-4332(97)00789-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The interaction of a variety of epoxy model molecules (representative of uncured, part-cured and fully-cured epoxy/polyamine adhesive/coating systems) with aluminium, anodised titanium and copper was examined using XPS. No interaction with epoxy functionalised molecules could be observed, but a strong interaction with nitrogenous molecules was noted. Copper surfaces were found to form copper-molecular complex films, whereas anodised titanium and aluminium appear to form adsorbed monolayers. However, the binding mechanism of these molecules on titanium and aluminium showed significant differences, with Bronsted (protonic) acid/base bonding more important on titanium than aluminium. (C) 1998 Elsevier Science B.V. All rights reserved.

引用

页码：270 / 286

页数：17

共 25 条

[1] Adsorption modes of a model adhesive resin, (methylamino)ethanol, on aluminum and phosphated aluminum surfaces [J].