Dye-Sensitized Solar Cells

被引:7190
作者
Hagfeldt, Anders [1 ,2 ,3 ]
Boschloo, Gerrit [1 ]
Sun, Licheng [2 ,3 ]
Kloo, Lars [2 ]
Pettersson, Henrik [4 ]
机构
[1] Uppsala Univ, Dept Phys & Analyt Chem, SE-75105 Uppsala, Sweden
[2] KTH Royal Inst Technol, Dept Chem, SE-10044 Stockholm, Sweden
[3] Dalian Univ Technol, State Key Lab Fine Chem, DUT KTH Joint Educ & Res Ctr Mol Devices, Dalian 116012, Peoples R China
[4] Swerea IVF AB, SE-43122 Molndal, Sweden
基金
瑞典研究理事会;
关键词
NANOCRYSTALLINE TIO2 FILMS; INTERFACIAL ELECTRON-TRANSFER; POLYMER GEL ELECTROLYTE; OPEN-CIRCUIT VOLTAGE; IONIC LIQUID ELECTROLYTES; PHOTOINDUCED ABSORPTION-SPECTROSCOPY; TRIPHENYLAMINE-BASED DYES; CONJUGATED ORGANIC-DYES; SOLID-STATE ELECTROLYTE; TITANIUM-DIOXIDE FILMS;
D O I
10.1021/cr900356p
中图分类号
O6 [化学];
学科分类号
070301 [无机化学];
摘要
Dye-sensitized solar cells (DSCs) offer the possibilities to design solar cells with a large flexibility in shape, color, and transparency. DSC research groups have been established around the world with biggest activities in Europe, Japan, Korea, China, and Australia. The sun emits light with a range of wavelengths from the ultraviolet and visible to the infrared. It peaks in the visible, resembling the spectrum of a blackbody at a temperature of 5760 K. It is, however, influenced by atmospheric absorption and the position of the sun. The advent of heteroleptic ruthenium complexes furnished with an antenna function has taken the performance of the DSC to a new level. Two examples of these dyes are Z991 and C101. Compared with the classical DSC Ru dyes, their extinction coefficients are higher and the spectral response is shifted to the red. The positions of the energy levels at the oxide/dye/electrolyte interface are fundamentally important to the function of the DSC.
引用
收藏
页码:6595 / 6663
页数:69
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