C-F bond activation in perfluorobenzothiolate compounds of Os(III).: X-ray structures of [Os(SC6F4(F-2))(SC6F5)2(PMe2Ph)2], [Os(SC6F5)2(o-S2C6F4)(PMe2Ph)] and [Os(C6F5)2(o-S2C6F4)(PMe2Ph)2]

被引：8

作者：

Arroyo, M

Bernes, S

Brianzo, JL

Mayoral, E

Richards, RL

Rius, J

Torrens, H ^{[1
]}

机构：

[1] Fac Quim, DEPg, Mexico City 04510, DF, Mexico

[2] BUAP, Inst Ciencias, Ctr Quim, Puebla 72570, Mexico

[3] UAB, Fac Ciencias, Unidad Cristalografia, Bellaterra, Spain

[4] John Innes Ctr, Norwich NR4 7UH, Norfolk, England

[5] Inst Ciencia Mat Barcelona, Bellaterra 08193, Spain

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 1998年 / 1卷 / 07期

关键词：

crystal structures; C-F bond activation; osmium complexes; perfluorobenzothiolate complexes;

D O I：

10.1016/S1387-7003(98)00067-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Thermolysis of [Os(SC6F4(F-2)) (SC6F5)(2)(PMe2Ph)(2)] (1) in refluxing toluene affords [Os(SC6F5)(2)(o-S2C6F4) (PMe2Ph)] (2) and [Os(C6F5)(2)(o-S2C6F4) (PMe2Ph)(2)] (3) through a process involving C-F cleavage as well as C-S bond formation. The X-ray structures of 1, 2 and 3 have been determined. In the solid state compound 1 shows a C-F --> Os interaction. (C) 1998 Elsevier Science S.A. All rights reserved.

引用

收藏

页码：273 / 276

页数：4

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