Microwave heating in the TS-1 catalyzed oxyfunctionalisation of n-hexane

被引：10

作者：

Kooyman, PJ

Luijkx, GCA

Arafat, A

vanBekkum, H

机构：

[1] Lab. of Organ. Chem. and Catalysis, Delft University of Technology, 2628 BL Delft

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1996年 / 111卷 / 1-2期

关键词：

TS-1; microwave heating; n-hexane oxyfunctionalisation; hydrogen peroxide;

D O I：

10.1016/1381-1169(96)00206-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Using the zeolite TS-1 catalyzed oxyfunctionalisation of n-hexane with aqueous hydrogen peroxide as a model reaction, the use of microwave heating is compared to conventional heating. Using microwave heating, hydrogen peroxide conversion is higher than using conventional heating, although the efficiency of incorporation of oxygen into n-hexane is lower. Adsorption measurements using an FT-IR microscope method reveal a synergism of adsorption into the zeolite between n-hexane and hydrogen peroxide.

引用

页码：167 / 174

页数：8

共 13 条

[1]

BAGHURST DR, 1992, J CHEM SOC CHEM COMM, P974

[2]

Besemer AC, 1993, THESIS DELFT U TECHN

[3]

CLERICI MG, 1991, APPL CATAL, V68, P98

[4] THE RAPID SYNTHESIS OF ORGANIC-COMPOUNDS IN MICROWAVE-OVENS [J].

GEDYE, RN ;

SMITH, FE ;

WESTAWAY, KC .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1988, 66 (01) :17-26

[5]

GRAEF M, 1979, PREPR DIV PAT CHEM A, V24, P432

[6]

HUYBRECHTS DRC, 1990, NATURE, V345, P146

[7]

KOOYMAN PJ, 1993, P 9 INT ZEOL C, V1, P505

[8] APPLICATIONS OF MICROWAVE DIELECTRIC HEATING EFFECTS TO SYNTHETIC PROBLEMS IN CHEMISTRY [J].

MINGOS, DMP ;

BAGHURST, DR .

CHEMICAL SOCIETY REVIEWS, 1991, 20 (01) :1-47

[9]

Smith K., 1992, SOLID SUPPORTS CATAL

[10]

TATSUMI T, 1991, CATAL SOC JPN, V33, P444

← 1 2 →