Design and synthesis of processible functional copolymers

被引：19

作者：

Dhanabalan, A ^{[1
]}

van Hal, PA ^{[1
]}

van Duren, JKJ ^{[1
]}

van Dongen, JLJ ^{[1
]}

Janssen, RAJ ^{[1
]}

机构：

[1] Eindhoven Univ Technol, Lab Macromol & Organ Chem, NL-5600 MB Eindhoven, Netherlands

来源：

SYNTHETIC METALS | 2001年 / 119卷 / 1-3期

关键词：

transition-metal catalyzed reactions; conjugated copolymer; mass spectroscopy; UV-vis-NIR absorption; photoluminescence; solar cells;

D O I：

10.1016/S0379-6779(00)01316-3

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Novel tailor-made AB, ABAC, and ABAA type heteroaromatic copolymers, in which B represents an N-alkylpyrrole unit, were synthesized via Pd-catalyzed Stille polymerization and characterized by a variety of analytical techniques. MALDI-TOF mass spectrometry allowed the detailed characterization of polymer weight and determination of end groups. By varying the nature of the repeating monomer units and their sequence, copolymers with promising properties for photovoltaic devices could be obtained.

引用

页码：169 / 170

页数：2