The first example of a double bridged diruthenium(II) complex containing the rare bridging S,O bidentate dimethyl sulfoxide ligand which defines a stable Ru-Cl-Ru-S-O five-membered ring

被引：23

作者：

Geremia, S ^{[1
]}

Mestroni, S ^{[1
]}

Calligaris, M ^{[1
]}

Alessio, E ^{[1
]}

机构：

[1] Univ Trieste, Dipartimento Sci Chim, I-34127 Trieste, Italy

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1998年 / 15期

关键词：

D O I：

10.1039/a804799e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The diruthenium(II) complex [Ru-2(mu-Cl)(mu-Me2SO-S, O)Cl-3(Me2SO-S)(3)(CO)(2)] has been synthesized from cis,fac-[RuCl2(Me2SO)(3)(CO)] in refluxing acetone and characterized by X-ray crystallography; unusual solution (H-1 and C-13 NMR) and solid-state (IR) spectral features were found for the bridging sulfoxide, besides a remarkable inertness towards substitution reactions.

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页码：2447 / 2448

页数：2

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