The effect of N-methylation on the chemical reactivity of binuclear Ni amine-thiophenolate complexes

被引：57

作者：

Kersting, B ^{[1
]}

Steinfeld, G ^{[1
]}

机构：

[1] Univ Freiburg, Inst Anorgan & Analyt Chem, D-79104 Freiburg, Germany

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 15期

关键词：

D O I：

10.1039/b103050g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Macrocyclic amine thiophenolate ligands are shown to form face-sharing bioctahedral nickel complexes with a central N3Ni(mu -SR)(2)(mu -Cl)NiN3 core structure. The bridging halide ion can be readily replaced when all six nitrogen atoms are tertiary amine donors.

引用

页码：1376 / 1377

页数：2

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