Application of polyelectrolytic temperature-responsive hydrogels in chemical sensors

被引:31
作者
Guenther, Margarita [1 ]
Gerlach, Gerald
Corten, Cathrin
Kuckling, Dirk
Mueller, Martin
Shi, Zhangman
Sorber, Joerg
Arndt, Karl-Friedrich
机构
[1] Tech Univ Dresden, Inst Solid State Electron, Helmholtzstr 10, D-01069 Dresden, Germany
[2] Tech Univ Dresden, Dept Chem & Food Chem, D-01069 Dresden, Germany
[3] Polymer Res Inst, D-01069 Dresden, Germany
关键词
ATR-FTIR spectroscopy; chemical sensor; pH-sensitive; polyelectrolytic hydrogel; swelling behaviour; temperature-sensitive;
D O I
10.1002/masy.200750846
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
A rapidly expanding field of on-line process monitoring and on-line control in biotechnology, food industry, pharmaceutical industry, process chemistry, environmental measuring technology, water treatment and sewage processing requires the development of new micro fabricated reliable chemical and biosensors that are specific for particular species and can attain the analytic information in a faster, simpler and cheaper manner. Using a functionalised polymer coating in sensors provides the possibility to detect, transmit and record the information regarding the concentration change or the presence of a specific analyte (a chemical or biological substance that needs to be measured) by producing a signal proportional to the concentration of the target analyte. However, the sensor response time and signal reproducibility are limited by the visco-elastical and hysteresis behaviour of the polymer material. We propose some methods improving the properties of the chemical sensors on the basis of thermo-shrinking N-isopropylacrylamicle (NIPAAm) copolymer gels.
引用
收藏
页码:314 / 321
页数:8
相关论文
共 11 条
[1]   LLS and FTIR studies on the hysteresis in association and dissociation of poly(N-isopropylacrylamide) chains in water [J].
Cheng, H ;
Shen, L ;
Wu, C .
MACROMOLECULES, 2006, 39 (06) :2325-2329
[2]  
FLORY PJ, 1953, PRINCIPLES POLYMER C
[3]  
GUENTHER M, 2006, IN PRESS SENS ACTUAT
[4]   ATR-FTIR spectroscopic study on hydrogen bonding of poly(N0-isopropylacrylamide-co-sodium acrylate) gel [J].
Hirashima, Y ;
Sato, H ;
Suzuki, A .
MACROMOLECULES, 2005, 38 (22) :9280-9286
[5]   Conformational change of poly(N-isopropylacrylamide) during the coil-globule transition investigated by attenuated total reflection/infrared spectroscopy and density functional theory calculation [J].
Katsumoto, Y ;
Tanaka, T ;
Sato, H ;
Ozaki, Y .
JOURNAL OF PHYSICAL CHEMISTRY A, 2002, 106 (14) :3429-3435
[6]   Synthesis of transition-metal-ion-selective poly(N-isopropylacrylamide) hydrogels by the incorporation of an aza crown ether [J].
Kuckling, D ;
Pareek, P .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2003, 41 (11) :1594-1602
[7]  
LANDAU LD, 1965, THEORY PHASE T
[8]   Change in hydration state during the coil-globule transition of aqueous solutions of poly(N-isopropylacrylamide) as evidenced by FTIR spectroscopy [J].
Maeda, Y ;
Higuchi, T ;
Ikeda, I .
LANGMUIR, 2000, 16 (19) :7503-7509
[9]   Thermodynamics of phase equilibrium for systems containing gels [J].
Maurer, G ;
Prausnitz, JM .
FLUID PHASE EQUILIBRIA, 1996, 115 (1-2) :113-133
[10]  
Muller M, 1998, MACROMOL RAPID COMM, V19, P333