Compartmental Schiff-base ligands-a rich library of tectons in designing magnetic and luminescent materials

被引：324

作者：

Andruh, Marius ^{[1
]}

机构：

[1] Univ Bucharest, Fac Chem, Inorgan Chem Lab, Bucharest 020464, Romania

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 11期

关键词：

SINGLE-MOLECULE MAGNETS; TETRANUCLEAR COPPER(II) COMPLEXES; SOLID-STATE ARCHITECTURES; CRYSTAL-STRUCTURES; COORDINATION POLYMERS; BINUCLEATING LIGANDS; ZN COMPLEXES; SUPRAMOLECULAR ORGANIZATION; HETEROBINUCLEAR COMPLEXES; ELECTROCHEMICAL-BEHAVIOR;

D O I：

10.1039/c0cc04506c

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

The binuclear complexes (3d-3d, 3d-3d', 3d-4f) with compartmental ligands can efficiently act as tectons in crystal engineering. Various high nuclearity clusters and coordination polymers can be easily obtained by choosing the appropriate spacers. The main interest in such systems arises from their magnetic and photophysical properties. Moreover, 3d-3d' and 3d-4f complexes are useful precursors in designing heterotrimetallic systems with relevance in molecular magnetism.

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页码：3025 / 3042

页数：18

相关论文

共 105 条

[1]

Binuclear complexes as tectons in designing supramolecular solid-state architectures [J].

Andruh, M .

PURE AND APPLIED CHEMISTRY, 2005, 77 (10) :1685-1706

[2]

OXOPHILY OF GADOLINIUM(III) AND SYNTHESIS OF DISSYMMETRIC DI(SCHIFF BASES) AND DISSYMMETRIC DINUCLEAR COMPOUNDS - CRYSTAL-STRUCTURE OF [CU2L'(OH)](CLO4)2.H2O WITH L'= 2-[N-(2-PYRIDYLETHYL)FORMIMIDOYL]-6-[N-((DIMETHYLAMINO)PROPYL)FORMIMIDOYL]PHENOLATO [J].

ANDRUH, M ;

KAHN, O ;

SAINTON, J ;

DROMZEE, Y ;

JEANNIN, S .

INORGANIC CHEMISTRY, 1993, 32 (09) :1623-1628

[3]

Crystal engineering of hybrid inorganic-organic systems based upon complexes with dissymmetric compartmental ligands [J].

Andruh, Marius ;

Branzea, Diana G. ;

Gheorghe, Ruxandra ;

Madalan, Augustin M. .

CRYSTENGCOMM, 2009, 11 (12) :2571-2584

[4]

3d-4f Combined Chemistry: Synthetic Strategies and Magnetic Properties [J].

Andruh, Marius ;

Costes, Jean-Pierre ;

Diaz, Carmen ;

Gao, Song .

INORGANIC CHEMISTRY, 2009, 48 (08) :3342-3359

[5]

Diphenoxo-bridged NiCo and CuCo complexes of macrocyclic ligands: synthesis, structure and electrochemical behaviour [J].

Aono, T ;

Wada, H ;

Yonemura, M ;

Furutachi, H ;

Ohba, M ;

Okawa, H .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (17) :3029-3034

[6]

Synthesis of 3d metallic single-molecule magnets [J].

Aromi, Guillem ;

Brechin, Euan K. .

SINGLE-MOLECULE MAGNETS AND RELATED PHENOMENA, 2006, 122 :1-67

[7]

Schiff-base compartmental macrocyclic complexes [J].

Atkins, AJ ;

Black, D ;

Blake, AJ ;

MarinBecerra, A ;

Parsons, S ;

RuizRamirez, L ;

Schroder, M .

CHEMICAL COMMUNICATIONS, 1996, (04) :457-464

[8]

Molecular architectures for trimetallic d/f/d complexes:: Structural and magnetic properties of a LnNi2 core [J].

Barta, Cheri A. ;

Bayly, Simon R. ;

Read, Paul W. ;

Patrick, Brian O. ;

Thompson, Robert C. ;

Orvig, Chris .

INORGANIC CHEMISTRY, 2008, 47 (07) :2280-2293

[9]

Batten SR, 1998, ANGEW CHEM INT EDIT, V37, P1460, DOI 10.1002/(SICI)1521-3773(19980619)37:11<1460::AID-ANIE1460>3.0.CO

[10]

2-Z

← 1 2 3 4 5 6 7 8 9 10 →