A cationic guest in a 24+ cationic host

被引：50

作者：

Bourgeois, JP

Fujita, M

Kawano, M

Sakamoto, S

Yamaguchi, K

机构：

[1] Univ Tokyo, CREST,JST, Dept Appl Chem, Sch Engn,Bunkyo Ku, Tokyo 1138656, Japan

[2] Chiba Univ, Ctr Chem Anal, Chiba 263, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2003年 / 125卷 / 31期

关键词：

D O I：

10.1021/ja0349002

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new tetrahedral coordination cage M12L6 was prepared from a linear dipyrimidine ligand (L) and cis-protected palladium(II) (M). This cage showed unprecedented host-guest chemistry where the cationic host accommodated a cationic guest despite 24+ charges on the host framework. The unusual cation-cation host-guest chemistry is described by a unique onionlike shell structure of the host-guest complex where two cationic spheres are mediated by an anionic sphere of a counteranion assembly. Copyright © 2003 American Chemical Society.

引用

页码：9260 / 9261

页数：2

共 29 条

[1] Chemical transformations within isolated nanospaces
Bourgeois, JP
Fujita, M
[J]. AUSTRALIAN JOURNAL OF CHEMISTRY, 2002, 55 (10) : 619 - 621
[2] Supermolecules by design
Caulder, DL
Raymond, KN
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1999, 32 (11) : 975 - 982
[3] Caulder DL, 1998, ANGEW CHEM INT EDIT, V37, P1840, DOI 10.1002/(SICI)1521-3773(19980803)37:13/14<1840::AID-ANIE1840>3.0.CO
[4] 2-D
[5] Self-assembling capsules
Conn, MM
Rebek, J
[J]. CHEMICAL REVIEWS, 1997, 97 (05) : 1647 - 1668
[6] Supramolecular arrays based on dimetal building units
Cotton, FA
Lin, C
Murillo, CA
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (10) : 759 - 771
[7] Cram D.J., 1994, CONTAINER MOL THEIR
[8] DRLJACA A, 1999, DALTON T
[9] Drljaca A, 2000, EUR J INORG CHEM, P2221
[10] Drljaca A, 1999, CHEM-EUR J, V5, P2295, DOI 10.1002/(SICI)1521-3765(19990802)5:8<2295::AID-CHEM2295>3.0.CO

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