Adsorption of selected toxic metals by modified peanut shells

The objective of this study was to modify peanut shells to enhance their adsorptive properties toward the metal ions cadmium (Cd2+), copper (Cu2+), nickel (Ni2+), lead (Pb2+) and zinc (Zn2+). Milled peanut shells were initially washed with water or 0.1N NaOH or left unwashed. Following these treatments or lack of treatment, the shells were either left unmodified or modified by a heat treatment in the presence of either 1.0M phosphoric acid or 0.6M citric acid. Modified peanut shells were evaluated either for adsorption efficiency or for adsorption capacity using the five metal ions listed above. Adsorption efficiencies and capacities were compared with efficiencies and/or capacities for the commercial chelating or cation exchange resins Amberlite 200, Amberlite IRC-718, Duolite GT-73, and carboxymethylcellulose. For the adsorption efficiencies of individual metal ions, modified peanut shells met or exceeded the adsorption values for cadmium, copper, nickel or zinc ions compared with the commercial resins Duolite GT-73 and carboxymethylcellulose. In a solution containing all five metal ions, modified peanut shells met or exceeded the adsorption efficiencies for cadmium, copper and lead ions compared with Duolite GT-73, Amberlite IRC-718 and carboxymethylcellulose. Adsorption capacities of modified peanut shells met or exceeded the adsorption capacity of Duolite GT-73 for lead ions only. Citric or phosphoric acid-modified peanut shells showed a preference for Cu2+ and Pb2+ and appear promising as potentially inexpensive adsorbents for selected metal ions. (C) 2001 Society of Chemical Industry.