CeCl3 and LaCl3 binary solutions as environment-friendly corrosion inhibitors of AA5083 Al-Mg alloy in NaCl solutions

被引:126
作者
Aballe, A [1 ]
Bethencourt, M [1 ]
Botana, FJ [1 ]
Marcos, M [1 ]
机构
[1] Univ Cadiz, Fac Ciencias Mar, Dept Ciencias Mat & Ingn Met & Quim Inorgan, Cadiz 11510, Spain
关键词
aluminium; green inhibitors; chromates; rare-earth;
D O I
10.1016/S0925-8388(01)01160-4
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Lanthanum and cerium chloride and their binary mixtures have been investigated as corrosion inhibitors of AA5083 Al-Mg alloy in aerated 3.5% NaCl aqueous solution. Their inhibitor power was evaluated by using electrochemical techniques together with full immersion tests. The highest protection degree was found for the binary solution doped with 250 ppm CeCl3 and 250 ppm LaCl3. Scanning electron microscopy and energy dispersive spectroscopy enabled us to confirm the cathodic nature of the inhibition process and to establish some features of the inhibition process. (C) 2001 Published by Elsevier Science B.V.
引用
收藏
页码:855 / 858
页数:4
相关论文
共 12 条
[1]  
ABALLE A, 1997, P EUR 97 TRONDH NORW, V2, P339
[2]  
[Anonymous], 1985, CERAMIC ENG SCI PROC
[3]   Inhibition of 5083 aluminium alloy and galvanised steel by lanthanide salts [J].
Arenas, MA ;
Bethencourt, M ;
Botana, FJ ;
de Damborenea, J ;
Marcos, M .
CORROSION SCIENCE, 2001, 43 (01) :157-170
[4]   Lanthanide compounds as environmentally-friendly corrosion inhibitors of aluminium alloys:: A review [J].
Bethencourt, M ;
Botana, FJ ;
Calvino, JJ ;
Marcos, M ;
Rodríguez-Chacón, MA .
CORROSION SCIENCE, 1998, 40 (11) :1803-1819
[5]   The influence of the surface distribution of Al6(MnFe) intermetallic on the electrochemical response of AA5083 aluminium alloy in NaCl solutions [J].
Bethencourt, M ;
Botana, FJ ;
Calvino, JJ ;
Marcos, M ;
Pérez, J ;
Rodríguez, MA .
ELECTROCHEMICAL METHODS IN CORROSION RESEARCH VI, PTS 1 AND 2, 1998, 289-2 :567-573
[6]   Protection against corrosion in marine environments of AA5083 Al-Mg alloy by lanthanide chlorides [J].
Bethencourt, M ;
Botana, FJ ;
Cauqui, MA ;
Marcos, M ;
Rodriguez, MA ;
RodriguezIzquierdo, JM .
JOURNAL OF ALLOYS AND COMPOUNDS, 1997, 250 (1-2) :455-460
[7]  
HARROP D, 1988, SPECIAL PUBLICATION, V71, P7
[8]  
Hinton B. R. W., 1986, Materials Forum, V9, P162
[9]  
HINTON BRW, 1984, MET FORUM, V7, P11
[10]  
Mansfeld F., 1994, British Corrosion Journal, V29, P194