Michael additions catalyzed by phosphines.: An overlooked synthetic method

被引：90

作者：

Gimbert, C ^{[1
]}

Lumbierres, M ^{[1
]}

Marchi, C ^{[1
]}

Moreno-Mañas, M ^{[1
]}

Sebastián, RM ^{[1
]}

Vallribera, A ^{[1
]}

机构：

[1] Univ Autonoma Barcelona, Dept Chem, E-08193 Barcelona, Spain

来源：

TETRAHEDRON | 2005年 / 61卷 / 36期

关键词：

organocatalysis; phosphines; conjugate addition; beta-dicarbonyl compounds;

D O I：

10.1016/j.tet.2005.07.005

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Triphenylphosphine and tributylphosphine are excellent catalysts for Michael additions. Many beta-dicarbonyl compounds and electron-poor olefins, including sterically demanding partners, react successfully. The Michael addition catalyzed by phosphines deserves attention in its own right as a useful synthetic method. (c) 2005 Elsevier Ltd. All rights reserved.

引用

页码：8598 / 8605

页数：8

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