High temperature oxidation of steels in air and CO2-O2 atmosphere

被引：14

作者：

Lee, DB ^{[1
]}

Choi, JW

机构：

[1] Sungkyunkwan Univ, Dept Adv Mat Engn, Suwon 440746, South Korea

[2] POSCO, Tech Res Labs, Gwangyang 545090, South Korea

来源：

OXIDATION OF METALS | 2005年 / 64卷 / 5-6期

关键词：

oxidation; steel; reheat furnace;

D O I：

10.1007/s11085-005-8530-8

中图分类号：

TF [冶金工业];

学科分类号：

0806 [冶金工程];

摘要：

Three kinds of hot rolled steel slabs, viz. high strength steel, bake hardened steel and low carbon steel, were oxidized isothermally between 1100 and 1250 degrees C for up to 2 hr in 1 atm of air and an 85%N-2-10%CO2-5%O-2 gas mixture. The steels were oxidized in a similar fashion in both the atmospheres. The oxidation process followed an initial linear rate law, which then gradually transformed to a nearly parabolic rate law. Thick, porous and nonadherent scales formed rapidly, due to the high oxidation temperature. The scales formed consisted of Fe2O3,(Fe2O3+Fe3O4), (Fe3O4+Fe2O3 +FeO) and (FeO+Fe3O4) from the outer surface. The presence of supersaturated oxygen beneath the scale resulted in grain boundary oxidation and the formation of internal oxide precipitates.

引用

页码：319 / 329

页数：11

共 18 条

[1]

The effect of oxygen concentration on the oxidation of low-carbon steel in the temperature range 1000 to 1250 degrees C [J].

Abuluwefa, H ;

Guthrie, RIL ;

Ajersch, F .

OXIDATION OF METALS, 1996, 46 (5-6) :423-440

[2]

Oxidation of low carbon steel in multicomponent gases .2. Reaction mechanisms during reheating [J].

Abuluwefa, HT ;

Guthrie, RIL ;

Ajersch, F .

METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE, 1997, 28 (08) :1643-1651

[3]

Oxidation of low carbon steel in multicomponent gases .1. Reaction mechanisms during isothermal oxidation [J].

Abuluwefa, HT ;

Guthrie, RIL ;

Ajersch, F .

METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE, 1997, 28 (08) :1633-1641

[4]

Birks N., 2012, INTRO HIGH TEMPERATU, DOI [10.1017/CBO9781139163903, DOI 10.1017/CBO9781139163903]

[5]

Structural characterization of yttrium-implanted pure iron and steels oxidized at high temperature [J].

Caudron, E ;

Buscail, H .

OXIDATION OF METALS, 2001, 55 (3-4) :261-277

[6]

Review of the high-temperature oxidation of iron and carbon steels in air or oxygen [J].

Chen, RY ;

Yuen, WYD .

OXIDATION OF METALS, 2003, 59 (5-6) :433-468

[7]

LONG-TIME OXIDATION OF IRON AT 1100-DEGREES-C IN AIR AS A FUNCTION OF TIME [J].

KUCERA, J ;

HAJDUGA, M .

OXIDATION OF METALS, 1994, 41 (1-2) :1-9

[8]

Logani R., 1969, OXID MET, V1, P3

[9]

KINETICS OF WUSTITE SCALE FORMATION ON IRON-NICKEL ALLOYS [J].

MORRIS, LA ;

SMELTZER, WW .

ACTA METALLURGICA, 1967, 15 (10) :1591-&

[10]

SELF-DIFFUSION AND DEFECT STRUCTURE IN COBALTOUS OXIDE [J].

MROWEC, S ;

PRZYBYLSKI, K .

OXIDATION OF METALS, 1977, 11 (06) :383-403

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