Modeling of Fischer-Tropsch synthesis in a slurry reactor with water permeable membrane

被引:8
作者
Fernandes, Fabiano A. N. [1 ]
机构
[1] Univ Fed Ceara, Dept Engn Quim, BR-60455760 Fortaleza, Ceara, Brazil
来源
JOURNAL OF NATURAL GAS CHEMISTRY | 2007年 / 16卷 / 02期
关键词
slurry reactor; membrane reactor; Fischer-Tropsch; modeling; PRODUCT GRADE OPTIMIZATION; IRON-BASED CATALYSTS;
D O I
10.1016/S1003-9953(07)60035-8
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Fischer-Tropsch synthesis is an important chemical process for the production of liquid fuels and olefins. In recent years, the abundant availability of natural gas and the increasing demand of olefins, diesel, and waxes have led to a high interest to further develop this process. A mathematical model of a slurry membrane reactor used for syngas polymerization was developed to simulate and compare the maximum yields and operating conditions in the reactor with that in a conventional slurry reactor. The carbon polymerization was studied from a modeling point of view in a slurry reactor with a water permeable membrane and a conventional slurry reactor. Simulation results show that different parameters affect syngas conversion and carbon product distribution, such as the hydrogen to carbon monoxide ratio, and the membrane parameters such as membrane permeance.
引用
收藏
页码:107 / 114
页数:8
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