Selectivity in the oxidation of limonene by amphiphilized metalloporphyrins in micellar media

被引：26

作者：

Borocci, S

Marotti, F

Mancini, G

Monti, D

Pastorini, A

机构：

[1] CNR, Ctr Studio Meccanismi Reaz, Dip Chim La Sapienza, I-00185 Rome, Italy

[2] Univ Roma La Sapienza, Dipartimento Chim, I-00185 Rome, Italy

[3] Univ Roma Tor Vergata, Dipartimento Sci & Tecnol Chim, I-00133 Rome, Italy

来源：

LANGMUIR | 2001年 / 17卷 / 23期

关键词：

D O I：

10.1021/la010082k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The weak interactions responsible for the aggregation and organization of micellar aggregates have been shown to control the regioselectivity of the epoxidation of limonene catalyzed by manganese porphyrins toward the endo double bond. The same reaction carried out in the presence of aggregates formed by sodium N-dodecanoyl-L-prolinate has shown the same regioselectivity, a selectivity toward the R enantiomer of limonene and a slight but significative stereoselectivity due to the organization of the molecular aggregates.

引用

页码：7198 / 7203

页数：6

共 43 条

[1] MONOOXYGENASE-LIKE OXIDATION OF HYDROCARBONS BY H2O2 CATALYZED BY MANGANESE PORPHYRINS AND IMIDAZOLE - SELECTION OF THE BEST CATALYTIC-SYSTEM AND NATURE OF THE ACTIVE OXYGEN SPECIES [J].