The first structurally characterised homoleptic organovanadium(III) compound

被引：25

作者：

Alonso, PJ ^{[1
]}

Forniés, J ^{[1
]}

García-Monforte, MA ^{[1
]}

Martín, A ^{[1
]}

Menjón, B ^{[1
]}

机构：

[1] Univ Zaragoza, Fac Ciencias, CSIC, Inst Ciencia Mat Aragon, E-50009 Zaragoza, Spain

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 20期

关键词：

D O I：

10.1039/b106364m

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The homoleptic, tetrahedral, paramagnetic d(2) species [NBu4][V-III (C6Cl5)(4)] 1 has been obtained and characterised by analytical, spectroscopic and X-ray diffraction methods.

引用

页码：2138 / 2139

页数：2

共 26 条

[1] SILYLMETHYL AND RELATED COMPLEXES .6. PREPARATION, PROPERTIES, AND CRYSTAL AND MOLECULAR-STRUCTURE OF TRIS[BIS(TRIMETHYLSILYL)METHYL]-CHROMIUM(III) - CHEMISTRY OF RELATED COMPOUNDS OF TITANIUM(III), VANADIUM(III), ZIRCONIUM(IV), AND HAFNIUM(IV) [J].

BARKER, GK ;

LAPPERT, MF ;

HOWARD, JAK .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1978, (07) :734-740

[2] SPECIAL ISSUE ON 2-MASS BENCHMARK [J].

BERNSTEIN, DS ;

WIE, B .

INTERNATIONAL JOURNAL OF ROBUST AND NONLINEAR CONTROL, 1995, 5 (01) :1-1

[3] ELECTRON-DEFICIENT VANADIUM ALKYL COMPLEXES - SYNTHESIS AND MOLECULAR-STRUCTURE OF THE VANADIUM(III) DINITROGEN COMPLEX [(ME3CCH2)3V]2(MU-N2) [J].

BUIJINK, JKF ;

MEETSMA, A ;

TEUBEN, JH .

ORGANOMETALLICS, 1993, 12 (06) :2004-2005

[4]

CONNELLY NG, 1982, COMPREHENSIVE ORGANO, V3, P647

[5] Stepwise reduction of dinitrogen occurring on a divanadium model compound: A synthetic, structural, magnetic, electrochemical, and theoretical investigation on the [V=N=N=V](n+) [n=4-6] based complexes [J].

Ferguson, R ;

Solari, E ;

Floriani, C ;

Osella, D ;

Ravera, M ;

Re, N ;

ChiesiVilla, N ;

Rizzoli, C .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (42) :10104-10115

[6] SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF THE FIRST ISOLATED HOMOLEPTIC ORGANOPLATINUM(IV) COMPOUND - [PT(C6CL5)(4)] [J].

FORNIES, J ;

MENJON, B ;

SANZCARRILLO, RM ;

TOMAS, M ;

CONNELLY, NG ;

CROSSLEY, JG ;

ORPEN, AG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (15) :4295-4304

[7] Synthesis and reactivity of mononuclear (pentachlorophenyl)rhodium(II) complexes. Structural relevance of rhodium-o-chlorine secondary bonding [J].

Garcia, MP ;

Jimenez, MV ;

Cuesta, A ;

Siurana, C ;

Oro, LA ;

Lahoz, FJ ;

Lopez, JA ;

Catalan, MP ;

Tiripicchio, A ;

Lanfranchi, M .

ORGANOMETALLICS, 1997, 16 (05) :1026-1036

[8]

GEARY WJ, 1971, COORDIN CHEM REV, V7, P8

[9] Vanadium complexes containing the 2,4,6-tris(trifluoromethyl)phenyl ('fluoromes') ligand [J].

Gibson, VC ;

Redshaw, C ;

Sequeira, LJ ;

Dillon, KB ;

Clegg, W ;

Elsegood, MRJ .

CHEMICAL COMMUNICATIONS, 1996, (18) :2151-2152

[10]

HEYN B, 1990, ANORGANISCHE SYNTHES, P18

← 1 2 3 →