Polyurethane-epoxy maleate of bisphenol A semi-interpenetrating polymer networks

被引:22
作者
Cascaval, CN [1 ]
Ciobanu, C [1 ]
Rosu, D [1 ]
Rosu, L [1 ]
机构
[1] Petru Poni Inst Macromol Chem, Iasi 6600, Romania
关键词
semi-interpenetrating polymer networks; polyurethane; epoxy maleate of bisphenol A; mechanical properties; swelling;
D O I
10.1002/app.2236
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Semi-interpenetrating polymer networks were synthesized starting from polyurethane (PU) and epoxy maleate of bisphenol A (EMBA). Differential scanning calorimetry and swelling measurements showed good miscibility and the presence of the strong intermolecular interactions within the synthesized networks. The physicomechanical properties increased against PU to a maximum value with the increasing of EMBA content up to 12 wt % and then decreased with further increasing EMBA content. Generally, with exception of the elongation at the limit of elasticity, the mechanical properties improved very much under action of the UV radiation. (C) 2002 John Wiley & Sons, Inc.
引用
收藏
页码:138 / 144
页数:7
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