Pt fibers with stacked donut-like mesospace by assembling Pt nanoparticles: Guided deposition in physically confined self-assembly of surfactants

被引:103
作者
Yamauchi, Yusuke [1 ]
Takai, Azusa [3 ]
Nagaura, Tomota [1 ,2 ]
Inoue, Satoru [1 ,2 ]
Kuroda, Kazuyuki [3 ]
机构
[1] Natl Inst Mat Sci, Nano Ceram Ctr, Int Ctr Mat Nanoarchitecton, WPI Res Ctr, Tsukuba, Ibaraki 3050044, Japan
[2] Univ Tsukuba, Grad Sch Pure & Appl Sci, Doctoral Program Mat Sci & Engn, Tsukuba, Ibaraki 3058577, Japan
[3] Waseda Univ, Fac Sci & Engn, Dept Appl Chem, Tokyo 1698555, Japan
关键词
D O I
10.1021/ja800269c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A stack donut-like mesospace is successfully introduced into Pt fibers by assembling Pt nanoparticles with uniform particle size, by utilizing the guided deposition of Pt nanoparticles in preferentially oriented liquid crystals. We clearly demonstrate that the collaboration of both LLC templating by electrochemical processes and hard templating utilizing a confined effect can lead to the genesis of new nanostructured metals. Such a unique metal-based nanoarchitecture enhances the surface area and enables the high-mass transportation of guest species. Preferentially oriented mesochannels should contribute significantly to the fine control and transport of electronic carriers through metal fibers.
引用
收藏
页码:5426 / +
页数:3
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