Two additive-induced isomeric aluminoborates templated by methylamine

被引：48

作者：

Cao, Gao-Juan ^{[1
]}

Lin, Jian ^{[3
]}

Wang, Jin-Yun ^{[1
]}

Zheng, Shou-Tian ^{[1
]}

Fang, Wei-Hui ^{[1
]}

Yang, Guo-Yu ^{[1
,2
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China

[2] Beijing Inst Technol, Dept Chem, Beijing 100081, Peoples R China

[3] Xiamen Univ, Xiamen 361005, Fujian, Peoples R China

来源：

DALTON TRANSACTIONS | 2010年 / 39卷 / 37期

关键词：

NONLINEAR-OPTICAL PROPERTIES; OPEN-FRAMEWORK; CRYSTAL-STRUCTURE; HELICAL CHANNELS; 1ST EXAMPLES; BOROGERMANATE; BORATE; BOROPHOSPHATE; TOPOLOGY; ZEOLITE;

D O I：

10.1039/c0dt00303d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two additive-induced isomeric aluminoborates, (CH3NH3)(2)(H2O)(2)[Al(B5O10)] (1) and (CH3NH3)(H2O)[Al(B5O10)] (2), have been obtained by using small methylamine molecules as structure directing agents (SDA) under solvothermal conditions and characterized by elemental analysis, IR, TGA, powder X-ray diffraction, single-crystal X-ray diffraction, NLO determination, UV-vis spectral investigation, electronic structure calculation and ion exchange. Different arrangements of B5O10 units and AlO4 tetrahedra results in two different structures with two pairs of helical channels along [100] and [010] directions, respectively. Interestingly, the two frameworks with noncentrosymmetric and chiral space groups separately exhibit the same diamond topologies and display good second harmonic generation efficiencies of about 2.0 times the value of KDP.

引用

页码：8631 / 8636

页数：6

共 56 条

[1]

[Anonymous], 1990, ACTA CRYSTALLOGR A

[2]

Becker P, 1998, ADV MATER, V10, P979, DOI 10.1002/(SICI)1521-4095(199809)10:13<979::AID-ADMA979>3.0.CO

[3]

2-N

[4] Template effect of chain-type polyamines on pore augmentation: Five open-framework zinc phosphates with 16-ring channels [J].

Chang, Wen-Ming ;

Cheng, Ming-Yu ;

Liao, Yueh-Chun ;

Chang, Ming-Chung ;

Wang, Sue-Lein .

CHEMISTRY OF MATERIALS, 2007, 19 (25) :6114-6119

[5] RECENT ADVANCES IN NONLINEAR OPTICAL AND ELECTROOPTICAL MATERIALS [J].

CHEN, CT ;

LIU, GZ .

ANNUAL REVIEW OF MATERIALS SCIENCE, 1986, 16 :203-243

[6] Controlled generation of heterochiral or homochiral coordination polymer: helical conformational polymorphs and argentophilicityinduced spontaneous resolution [J].

Chen, XD ;

Du, M ;

Mak, TCW .

CHEMICAL COMMUNICATIONS, 2005, (35) :4417-4419

[7]

Dadachov MS, 2000, ANGEW CHEM INT EDIT, V39, P3674, DOI 10.1002/1521-3773(20001016)39:20<3674::AID-ANIE3674>3.0.CO

[8]

2-W

[9] A high-silica zeolite with a 14-tetrahedral-atom pore opening [J].

Freyhardt, CC ;

Tsapatsis, M ;

Lobo, RF ;

Balkus, KJ ;

Davis, ME .

NATURE, 1996, 381 (6580) :295-298

[10] Synthesis and structure of an aluminum borate chloride consisting of 12-membered borate rings and aluminate clusters [J].

Gao, Wenliang ;

Wang, Yingxia ;

Li, Guobao ;

Liao, Fuhui ;

You, Liping ;

Lin, Jianhua .

INORGANIC CHEMISTRY, 2008, 47 (16) :7080-7082

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