On the error structure of impedance measurements -: Series expansions

被引：7

作者：

Carson, SL ^{[1
]}

Orazem, ME

Crisalle, OD

García-Rubio, L

机构：

[1] Univ Florida, Dept Chem Engn, Gainesville, FL 32611 USA

[2] Univ S Florida, Dept Chem Engn, Tampa, FL 33620 USA

来源：

JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 2003年 / 150卷 / 10期

关键词：

D O I：

10.1149/1.1605421

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

A framework is presented for characterizing the statistical properties of frequency-domain measurements. The correlation between the variance in the complex impedance and the variances in the complex current and voltage are examined by means of a Taylor series expansion for the impedance. Both sufficient-only and necessary and sufficient conditions for equality of the variances of real and imaginary impedance are identified and verified using stochastic simulations of techniques commonly employed in frequency-domain measurements. (C) 2003 The Electrochemical Society.

引用

页码：E501 / E511

页数：11

共 39 条

[1] Thermoelectrochemical transfer function under thermal laminar free convection at a vertical electrode [J].

Aaboubi, O ;

Citti, I ;

Chopart, JP ;

Gabrielli, C ;

Olivier, A ;

Tribollet, B .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2000, 147 (10) :3808-3815

[2] MEASUREMENT MODELS FOR ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY .1. DEMONSTRATION OF APPLICABILITY [J].

AGARWAL, P ;

ORAZEM, ME ;

GARCIARUBIO, LH .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1992, 139 (07) :1917-1927

[3] APPLICATION OF MEASUREMENT MODELS FOR ANALYSIS OF IMPEDANCE SPECTRA [J].

AGARWAL, P ;

MOGHISSI, OC ;

ORAZEM, ME ;

GARCIARUBIO, LH .

CORROSION, 1993, 49 (04) :278-289

[4] Application of measurement models to impedance spectroscopy .2. Determination of the stochastic contribution to the error structure [J].

Agarwal, P ;

Crisalle, OD ;

Orazem, ME ;

GarciaRubio, LH .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1995, 142 (12) :4149-4158

[5] Application of measurement models to impedance spectroscopy .3. Evaluation of consistency with the Kramers-Kronig relations [J].

Agarwal, P ;

Orazem, ME ;

GarciaRubio, LH .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1995, 142 (12) :4159-4168

[6] A new experimental approach to the time-constants of electrochemical impedance:: frequency response of the double layer capacitance [J].

Antaño-Lopez, R ;

Keddam, M ;

Takenouti, H .

ELECTROCHIMICA ACTA, 2001, 46 (24-25) :3611-3617

[7] AC-RESPONSE OF A ROTATING-RING-DISK ELECTRODE - APPLICATION TO 2-D AND 3-D FILM FORMATION IN ANODIC PROCESSES [J].

BENZEKRI, N ;

KEDDAM, M ;

TAKENOUTI, H .

ELECTROCHIMICA ACTA, 1989, 34 (08) :1159-1166

[8] Noise resistance applied to corrosion measurements .3. Influence of the instrumental noise on the measurements [J].

Bertocci, U ;

Huet, F .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (08) :2786-2793

[9]

Box G. E. P., 1978, STAT EXPT INTRO DESI

[10]

Brandt S, 1999, STAT COMPUTATIONAL M

← 1 2 3 4 →