Transformations of a macrocyclic cyclophane belt into advanced [8]cyclacene and [8]cyclacene triquinone precursors

被引：79

作者：

Cory, RM

McPhail, CL

机构：

[1] Department of Chemistry, University of Western Ontario, London

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 12期

关键词：

D O I：

10.1016/0040-4039(96)00264-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Belt-shaped cyclophane 2, is converted to a naphthalene-containing belt-shaped cyclophane by dehydrogenation, to an unexpected bisdiene-containing belt-shaped cyclophane by epoxidation and dehydration, and to an unexpected anthraquinone-containing belt-shaped cyclophane by PCC oxidation. The latter cyclophane could be functionalized further by a surprising oxidation involving sequential dehydrogenation and conjugate addition of ethoxide.

引用

页码：1987 / 1990

页数：4

共 4 条

[1] FORCE-FIELD CALCULATIONS ON MOLECULAR BELTS BUILT FROM CYCLOHEXA-1,4-DIENE RINGS [J].