Polymerization of a thiol-bound styrene monolayer

被引：44

作者：

Ford, JF ^{[1
]}

Vickers, TJ ^{[1
]}

Mann, CK ^{[1
]}

Schlenoff, JB ^{[1
]}

机构：

[1] FLORIDA STATE UNIV,DEPT CHEM,TALLAHASSEE,FL 32306

来源：

LANGMUIR | 1996年 / 12卷 / 08期

关键词：

D O I：

10.1021/la950913k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The polymerization of a self-assembled monolayer of (mercaptomethyl)styrene is monitored in situ with surface enhanced Raman spectroscopy. Chemisorption of this thiol-containing styrene involves the loss of the S-H bond. The vinyl stretching mode at 1625 cm(-1), which disappears during both azo- and photoinitiated surface polymerization, is used to follow the kinetics of the process. Laser desorption/Fourier-transform ion cyclotron resonance/mass spectrometry confirms the transformation of the initiated monomer into a nondesorbable species.

引用

页码：1944 / 1946

页数：3

共 53 条

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