Covalent Attachment of a Rhenium Bipyridyl CO2 Reduction Catalyst to Rutile TiO2

被引：95

作者：

Anfuso, Chantelle L. ^{[2
]}

Snoeberger, Robert C., III ^{[1
]}

Ricks, Allen M. ^{[2
]}

Liu, Weimin ^{[2
]}

Xiao, Dequan ^{[1
]}

Batista, Victor S. ^{[1
]}

Lian, Tianquan ^{[2
]}

机构：

[1] Yale Univ, Dept Chem, New Haven, CT 06520 USA

[2] Emory Univ, Dept Chem, Atlanta, GA 30322 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2011年 / 133卷 / 18期

基金：

美国国家科学基金会;

关键词：

GENERATION VIBRATIONAL SPECTROSCOPY; EXCITED-STATES; ELECTRON-TRANSFER; RESONANCE-RAMAN; CARBON-DIOXIDE; ELECTROCATALYTIC REDUCTION; ELECTROCHEMICAL REDUCTION; RE-RE; COMPLEXES; SURFACE;

D O I：

10.1021/ja2013664

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We have characterized the covalent binding of the CO2 reduction electrocatalyst ReC0A (Re(CO)(3)-Cl(dcbpy) (dcbpy =4,4'-dicarboxy-2,2'-bipyridine)) to the TiO2 rutile (001) surface. The analysis based on sum frequency generation (SFG) spectroscopy and density functional theory (DFT) calculations indicates that ReC0A binds to TiO2 through the carboxylate groups in bidentate or tridentate linkage motifs. The adsorbed complex has the dcbpy moiety nearly perpendicular to the TiO2 surface and the Re exposed to the solution in a configuration suitable for catalysis.

引用

收藏

页码：6922 / 6925

页数：4

相关论文

共 37 条

[1] Ultrafast surface vibrational dynamics [J].

Arnolds, Heike ;

Bonn, Mischa .

SURFACE SCIENCE REPORTS, 2010, 65 (02) :45-66

[2] Time-dependent vibration Stokes shift during solvation: Experiment and theory [J].

Asbury, JB ;

Wang, YQ ;

Lian, TQ .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2002, 75 (05) :973-983

[3] EFFECTS OF CO ON THE ELECTROCATALYTIC ACTIVITY OF NI (CYCLAM)(2+) TOWARD THE REDUCTION OF CO2 [J].

BALAZS, GB ;

ANSON, FC .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1993, 361 (1-2) :149-157

[4] Electrocatalytic and homogeneous approaches to conversion of CO2 to liquid fuels [J].

Benson, Eric E. ;

Kubiak, Clifford P. ;

Sathrum, Aaron J. ;

Smieja, Jonathan M. .

CHEMICAL SOCIETY REVIEWS, 2009, 38 (01) :89-99

[5] When the Solute Becomes the Solvent: Orientation, Ordering, and Structure of Binary Mixtures of 1-Hexanol and Cyclohexane over the (0001) α-Al2O3 Surface [J].

Buchbinder, Avram M. ;

Weitz, Eric ;

Geiger, Franz M. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (41) :14661-14668

[6] Efficiency enhancement of the electrocatalytic reduction of CO2:: fac-[Re(v-bpy)(CO)3Cl] electropolymerized onto mesoporous TiO2 electrodes [J].

Cecchet, Francesca ;

Alebbi, Monica ;

Bignozzi, Carlo Alberto ;

Paolucci, Francesco .

INORGANICA CHIMICA ACTA, 2006, 359 (12) :3871-3874

[7] Studies of polymer surfaces by sum frequency generation vibrational spectroscopy [J].

Chen, Z ;

Shen, YR ;

Somorjai, GA .

ANNUAL REVIEW OF PHYSICAL CHEMISTRY, 2002, 53 :437-465

[8] The surface science of titanium dioxide [J].

Diebold, U .

SURFACE SCIENCE REPORTS, 2003, 48 (5-8) :53-229

[9] Interfacial Organization of Acetonitrile: Simulation and Experiment [J].

Ding, Feng ;

Hu, Zhonghan ;

Zhong, Qin ;

Manfred, Katherine ;

Gattass, Rafael R. ;

Brindza, Michael R. ;

Fourkas, John T. ;

Walker, Robert A. ;

Weeks, John D. .

JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (41) :17651-17659

[10] Theoretical studies of photoinduced electron transfer in dye-sensitized TiO2 [J].

Duncan, Walter R. ;

Prezhdo, Oleg V. .

ANNUAL REVIEW OF PHYSICAL CHEMISTRY, 2007, 58 :143-184

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