Raman signature of polyamorphism in triphenyl phosphite

被引:84
作者
Hedoux, A [1 ]
Guinet, Y [1 ]
Descamps, M [1 ]
机构
[1] Univ Lille 1, Lab Dynam & Struct Mat Mol, UFR Phys, URA 801, F-59655 Villeneuve Dascq, France
来源
PHYSICAL REVIEW B | 1998年 / 58卷 / 01期
关键词
D O I
10.1103/PhysRevB.58.31
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The polyamorphism of triphenyl phosphite has been investigated from a low-frequency Raman-scattering study. Interesting features about glaciation processes have been revealed from a study of the boson peak and an analysis of the Raman susceptibility in the glacial and crystalline states. The very close correspondence between the phonon peaks observed in the crystal and the Raman spectrum of the glacial state, as well as some contradictions about the fragility of the glacial state, if it is considered as amorphous, lead us to favor the description of the glacial state in terms of nanocrystallized domains. [S0163-1829(98)01925-0].
引用
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页码:31 / 34
页数:4
相关论文
共 21 条
[1]   CORRELATION-EFFECTS ON RAMAN-SCATTERING FROM LOW-ENERGY VIBRATIONAL-MODES IN GLASSES .2. EXPERIMENTAL RESULTS [J].
ACHIBAT, T ;
BOUKENTER, A ;
DUVAL, E .
JOURNAL OF CHEMICAL PHYSICS, 1993, 99 (03) :2046-2051
[2]  
AlbaSimionesco C, 1996, J RAMAN SPECTROSC, V27, P715, DOI 10.1002/(SICI)1097-4555(199610)27:10<715::AID-JRS32>3.0.CO
[3]  
2-6
[4]   A low-temperature amorphous phase in a fragile glass-forming substance [J].
Cohen, I ;
Ha, A ;
Zhao, XL ;
Lee, M ;
Fischer, T ;
Strouse, MJ ;
Kivelson, D .
JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (20) :8518-8526
[5]   LIGHT-SCATTERING SPECTROSCOPY OF THE LIQUID-GLASS TRANSITION IN CAKNO3 AND IN THE MOLECULAR GLASS SALOL - EXTENDED-MODE-COUPLING-THEORY ANALYSIS [J].
CUMMINS, HZ ;
DU, WM ;
FUCHS, M ;
GOTZE, W ;
HILDEBRAND, S ;
LATZ, A ;
LI, G ;
TAO, NJ .
PHYSICAL REVIEW E, 1993, 47 (06) :4223-4239
[6]   VIBRATION EIGENMODES AND SIZE OF MICROCRYSTALLITES IN GLASS - OBSERVATION BY VERY-LOW-FREQUENCY RAMAN-SCATTERING [J].
DUVAL, E ;
BOUKENTER, A ;
CHAMPAGNON, B .
PHYSICAL REVIEW LETTERS, 1986, 56 (19) :2052-2055
[7]   CORRELATION-EFFECTS ON RAMAN-SCATTERING FROM LOW-ENERGY VIBRATIONAL-MODES IN FRACTAL AND DISORDERED-SYSTEMS .1. THEORY [J].
DUVAL, E ;
GARCIA, N ;
BOUKENTER, A ;
SERUGHETTI, J .
JOURNAL OF CHEMICAL PHYSICS, 1993, 99 (03) :2040-2045
[8]   Supercooled liquids and polyamorphism [J].
Ha, A ;
Cohen, I ;
Zhao, XL ;
Lee, M ;
Kivelson, D .
JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (01) :1-4
[9]  
KRUGER M, 1992, J CHEM PHYS, V96, P7352, DOI 10.1063/1.462438
[10]   LIGHT-SCATTERING INVESTIGATION OF ALPHA-RELAXATION AND BETA-RELAXATION NEAR THE LIQUID-GLASS TRANSITION OF THE MOLECULAR GLASS SALOL [J].
LI, G ;
DU, WM ;
SAKAI, A ;
CUMMINS, HZ .
PHYSICAL REVIEW A, 1992, 46 (06) :3343-3356