1,4-diazoniabicyclo[2.2.2]octane tetrachlorocobaltate

被引：14

作者：

Bremner, CA ^{[1
]}

Harrison, WTA ^{[1
]}

机构：

[1] Univ Aberdeen, Dept Chem, Aberdeen AB24 3UE, Scotland

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2003年 / 59卷

关键词：

D O I：

10.1107/S1600536803011668

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, (C6H14N2)[CoCl4], is isostructural with (C6H14N2)[MCl4] (M = Cu, Zn) and contains doubly protonated dabconium C6H14N22+ cations and [CoCl4](2-) tetrahedra. These species interact by way of bifurcated N - H...(Cl, Cl) hydrogen bonds to form corrugated chains. The chains interact by way of van der Waals forces and C - H...Cl hydrogen bonds.

引用

页码：M425 / M426

页数：2

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