Synthesis and characterization of the monomeric molybdenum trithiolate Mo(η7-dmpt)(η1-dmpt)2 (dmpt = 2,6-dimesitylphenylthiolate)

被引：18

作者：

Buyuktas, BS ^{[1
]}

Olmstead, MM ^{[1
]}

Power, PP ^{[1
]}

机构：

[1] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 16期

关键词：

D O I：

10.1039/a803064b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of MoCl3(THF)(3) with 3 equiv, of LiSC(6)H(3)Mes(2)-2 2,6 (Mes = C6H2Me3-2,4,6) (Lidmpt) affords the monomeric molybdenum trithiolate Mo(eta(7)-dmpt)(eta(1)-dmpt)(2), 1, which is spectroscopically and structurally characterized; the MoS3 array has distorted trigonal pyramidal geometry which is caused by strong pi-interactions between molybdenum and an ortho-mesityl group from one of the thiolate substituents.

引用

页码：1689 / 1690

页数：2

共 19 条

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